Photoinduced toxicity single and binary mixtures of four polycyclic aromatic hydrocarbons to the marine diatom Skeletonema costatum

Diatom Skeletonema costatum Cleve is one of the main predominant phytoplankton species in the Changjiang Estuary in China. In order to provide some basic information for future assessment of the potential risk on phytoplankton communities in this estuary caused by polycyclic aromatic hydrocarbons(PAHs), this alga was selected as a representative to investigate the photoinduced toxicity of PAHs, in single and mixture. Four PAHs including three-ring phenanthrene and anthracene, four-ring fluoranthene and pyrene were tested in the laboratory. The single toxicity of each PAH on this microalga was compared with and without the simulated solar UV radiation. The results showed that this microalga was sensitive to PAH's photoinduced toxicity. Ratios of the 72 h median effect concentration obtained for fluorescent and UV light tests were about 8.4 for phenanthrene, 13.0 for anthracene, 6.5 for fluoranthene, and 5.7 for pyrene, indicating that UV light enhanced the PAH toxicity to this alga significantly. Under the fluorescent radiation (lacking UV), the dose-response curves based on chemical concentrations revealed that the order of toxic strength was fluoranthene greater than pyrene greater than anthracene greater than phenanthrene; while under the UV radiation (476 μW/cm2 for UVA, 6.5 μW/cm2 for UVB) it became fluoranthene approximately equaling anthracene greater than pyrene greater than phenanthrene, indicating that the UV light also changed its relative toxicity to this alga. The photoinduced toxicity of PAHs to the marine diatom S. costatum might be a synergistic effect of photosensitization reactions (e.g., generation of single-state oxygen) and photomodification (photooxidation and/or photolysis).The combined effects of six binary mixtures on the marine diatom S. costatum were investigated using the additive-index method. Four binary-mixtures (phenanthrene plus anthracene; phenanthrene plus pyrene; anthracene plus fluoranthene; anthracene plus pyrene) were found to be synergistic joint action mode, while two binary-mixtures (phenanthrene plus fluoranthene; fluoranthene plus pyrene) displayed antagonist, revealing a complex pattern of possible interactions. The combined action mode of PAHs might be related to various factors such as the mixture compounds, mixture ratios and test conditions, etc.     

南海中沙天然气水合物资源远景区海底沉积物的物理力学性质研究

根据南海中沙天然气水合物远景区沉积物样品的分析资料,从物理力学特征各方面对本区海底沉积物进行了综合工程地质特征研究。结果表明,本区海底沉积物类型全部为淤泥,工程地质性质相近,以高含水率、高孔隙比、低密度及高塑性为主要特征,抗剪强度很小,压缩系数均大于0.5。土体沉积环境为水动力强度较弱的深海半深海环境。     

金衢盆地第四纪红土沉积粒度组成特征

浙江金衢盆地第四纪红土分布广泛,是开展红土与全球变化研究的理想场所之一。汤溪红土沉积剖面的粒度组成研究表明:砂(>63μm)含量极少,平均1.58%,粉砂(4~63μm)和黏粒(<4μm)为众数粒组,其含量的平均值分别为48.51%和49.91%,频率曲线呈双峰式,推测红土母质具风成特性,沉积后经历了较强的风化成壤作用;均质红土与网纹红土具有相似的粒度分布特征,但网纹红土的分选更为复杂,底部有近源物质的混入;汤溪红土粒度的纵向变化旋回和纵向变化趋势,可能指示了中更新世以来南方气候的不稳定性和气候逐渐变干冷的趋势。     

软粘土中插入式大直径薄壁圆筒结构的一种极限状态分析模型

根据插入式大直径薄壁圆筒结构的工作特点建立了其合理的破坏机制，以此为基础建立了受横向荷载作用的插入式大直径薄壁圆筒结构的上限法极限分析模型，从中可以得到作用于插入式大直径薄壁圆筒结构上的横向极限荷载近似的上限解；并根据上限法模型计算结果，提出了计算受横向荷载作用的插入式大圆筒结构侧壁极限抗力的简化修正模型，利用此修正模型，基于极限平衡法，可以求解作用于插入式大直径薄壁圆筒结构上的横向极限荷载。     

Application of LICOM to the numerical study of the water exchangebetween the South China Sea and its adjacent oceans

1 IntroductionThe South China Sea (SCS) is the largestmarginal sea in the western Pacific (see Fig. 1). It con-nects with the SCS through the Taiwan Strait, with thePacific through the Luzon Strait, with the Sulu Seathrough the Mindoro and Balabac Straits and with theJava Sea and Andaman Sea through the Sunda Shelf(For convenience, here we refer to the section at 1.5°N,Fig. 2). It is shown that the seasonal SCS circulation ismostly affected by the summer/winter monsoon, andthe no…     

溴素的有机化学──Ⅴ.溴代脂肪酸—2,3,5,6—四溴—1,4—苯二酯的合成

以1，4—苯二酚和不同的短链脂肪酸为基本原料，经溴代、加成、形成酰卤和酰化等反应，合成了六种新的溴化脂肪酸—2，3，5，6—四溴—1，4—苯二酯。通过对产物的碳、氢、溴等元素的定量分析，以及红外吸收光谱和氢核磁共振谱的研究，验证了化合物的结构。     

中国沿海星虫动物门名录

取1980～1989年间在我国沿海进行星虫动物区系调查的标本和有关资料做了整理、鉴定,共39种,分隶于2纲,4目,6科,12属。其中1种在我国为首次记录。     

Simulations of Annual Cycle of Phytoplankton Production and the Utilization of Nitrogen in the Yellow Sea

A nutrient dynamic model coupled with a 3D physical model has been developed to study the annual cycle of phytoplankton production in the Yellow Sea. The biological model involves interactions between inorganic nitrogen (nitrate and ammonium), phosphate and phytoplankton biomass. The model successfully reproduces the main features of phytoplankton-nutrient variation and dynamics of production. 1. The well-mixed coastal water is characterized by high primary production, as well as high new production. 2. In summer, the convergence of tidal front is an important hydrodynamic process, which contributes to high biomass at frontal areas. 3. The evolution of phytoplankton blooms and thermocline in the central region demonstrate that mixing is a dominant factor to the production in the Yellow Sea. In this simulation, nitrate- and ammonium-based productions are estimated regionally and temporally. The northern Yellow Sea is one of the highly ranked regions in the Yellow Sea for the capability of fixing carbon and nitrogen. The annual averaged f-ratio of 0.37 indicates that regenerated production prevails over the Yellow Sea. The result also shows that phosphate is the major nutrient, limiting phytoplankton growth throughout the year and it can be an indicator to predict the bloom magnitude. Finally, the relative roles of external nutrient sources have been evaluated, and benthic fluxes might play a significant role in compensating 54.6% of new nitrogen for new production consumption.     

海洋环流模式中不同近似假设下的海表高度

Boussinesq近似是现代海洋环流模式中经常采用的假设，但随着海洋模式的不断发展完善以及气候研究应用的需要，有必要估算Boussinesq近似造成的模式误差。分别利用一个非Boussinesq近似的海洋模式与另一个结构相同且采用Boussinesq近似的模式计算海表高度，并同时利用模式预报的温度、盐度资料计算了比容异常高度。分析结果显示，这3种不同定义的海表高度无论空间结构，还是时间演变，都基本类似，尤其在热带海区最接近，差值≤1cm。Boussinesq近似意味着在模式中以体积守恒代替质量守恒，通常的做法是对其进行简单的质量补偿来保持质量守恒。比较说明，以质量补偿方法进行的高度订正对减小Boussinesq近似带来的误差没有本质的意义。     

Fuzzy Fatigue Reliability Analysis of Offshore Platforms in Ice-Infested Waters

1 .IntroductionTheBohaiGulfisinfestedbyiceinthewholewinter,andoffshorestructuresthereexperiencenotonlywind ,waves ,currentsandearthquake ,butalsoiceloadswhicharecomplicatedbecauseofthedynamicinteractionbetweenicesheetsandstructures.Duanetal.( 2 0 0 0 )hadacomprehensivere viewofthelatestadvancesonice inducedvibration ,fatigueandfractureofoffshorestructures ,payingmuchattentiontothedifferencesinicebreakingmodeanddynamicsofstructuresindifferentice in festedwaters .Theypresentedcriticallythelates…